| Hierarchical Cooperative Binary Ionic Porphyrin Nanocomposites, Tian, Y.; Busani, T.; Uyeda, G. H.; Martin, K. E.; van Swol, F.; Medforth, C. J.; Montaņo, G. A.; Shelnutt, J. A., Chem. Commun., 2012, 48, 4863-4865. HybridCBI.pdf HybridCBI-SI.pdf |
| Binary Ionic Porphyrin Nanosheets: Electronic and Light-harvesting Properties Regulated by Crystal Structure, Tian, Y.; Beavers, C.; Busani, T.; Martin, K. E.; Jacobsen, J. L.; B. Mercado, Swartzentruber, B. S.; van Swol, F.; Medforth, C. J.; Shelnutt, J. A., Nanoscale, 2012, 4, 1695-1700. CBI-crystal.pdf CBI-crystal-SI.pdf |
| Self-Assembled Porphyrin Nanostructures and their Potential Applications, Shelnutt, J. A.; Medforth, C. J., in "Organic Nanomaterials" Eds.: Torres, T.; Bottari, G., 2012, Wiley, in press. |
| Evolution of Dendritic Nanosheets into Durable Holey Sheets: A Lattice Gas Simulation Study, Challa, S. R.; Song, Y.; Shelnutt, J. A..; Miller, J. E.; van Swol, F., J. Porphyrins Phthalocyanines 2011, 15, 449-466. Dedicated to John Shelnutt on his 65th birthday. HoleySheets-2.pdf |
| Morphological Families of Self-Assembled Porphyrin Structures and their Photosensitization of Hydrogen Generation, Tian, Y.; Martin, K. E.; Shelnutt, J. Y.-T.; Evans, L.; Busani, T.; Miller, J. E.; Medforth, C. J.; Shelnutt, J. A., Chem. Commun. 2011, 47, 6069-6071. H2-Generation.pdf H2-Gen-SI.pdf |
| Steric Bulkiness of Pyrrole Substituents and the Out-of-Plane Deformations of Porphyrins: Nickel(II) Octaisopropylporphyrin and its Meso-Nitro Derivative, Haddad, R.; Lu, Y.; Quirke, J. M. E.; Berget, P.; Sun, L.; Leung, K.; Qiu, Y.; van Swol, F.; Medforth, C. J.; Shelnutt, J. A., J. Porphyrins Phthalocyanines 2011, 15, 727-741. S1088424611003707. Dedicated to Karl Kadish on his 65th birthday. |
| Templated Growth of Platinum Nanowheels Using the Inhomogeneous Reaction Environment of Bicelles, Garcia, R.M.; Song, Y.; Dorin, R. M.; Wang, H.; Moreno, A. M.; Jiang, Y.-B.; Tian, Y.; Qiu, Y.; Medforth, C. J.; Coker, E. N.; van Swol, F.; Miller, J. E.; Shelnutt, J. A., Phys. Chem. Chem. Phys. 2011, 13, 4846-4852. Nanowheels-2.pdf |
| Self-Assembled Porphyrin Nanostructures, Medforth, C. J.; Shelnutt, J. A. in "Handbook of Porphyrin Science" Eds. Kadish, K. M.; Smith, K. M.; Guilard, R., 2011, Vol. 11, World Scientific Publishing Company, Hackensack, NJ, Chpt. 50, 181-222. |
| Nickel(II) Chelatase Variants Directly Evolved from Murine Ferrochelatase: Porphyrin Distortion and Kinetic Mechanism, McIntyre, N. R.; Franco, R.; Shelnutt, J. A.; Ferreira, G. C., Biochemistry 2011, 50, 1535–1544. NiChelatase.pdf |
| Donor-Acceptor Biomorphs from the Ionic Self-assembly of Porphyrins, Martin, K. E.; Wang, Z.; Busani, T.; Garcia, R. M.; Chen, Z.; Jiang, Y.; Song, Y.; Jacobsen, J. L.; Vu, T. T.; Schore, N. E.; Swartzentruber, B. S.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2010, 132, 8194-8201. Biomorphs.pdf Biomorphs-SI.pdf |
| One Pot Synthesis of Triangular Gold Nanoplates Allowing Broad and Fine Tuning of Edge Length, Miranda, A.; Malheiro, E.; Skiba, E.; Quaresma, P.; Carvalho, P. A.; Eaton, P.; de Castro, B.; Shelnutt, J. A.; Pereira, E., Nanoscale 2010, 2, 2209-2216. Triangles.pdf Triangles-SI.pdf |
| Cobalt-Porphyrin Catalyzed Electrochemical Reduction of Carbon Dioxide in Water. 2. Mechanism from First Principles, Leung, K.; Nielsen, I. M. B.; Sai, N.; Medforth, C. J.; Shelnutt, J., J. Phys. Chem. A, 2010, 37, 10174. Paper 2.pdf Also, see paper Paper 1. A Density Functional Study of Intermediates. |
| Molecular Organization in Self-Assembled Binary Porphyrin Nanotubes Revealed by Resonance Raman Spectroscopy, Franco, R.; Jacobsen, J.; Wang, H.; Wang, Z.; Istvan, K.; Schore, N. E.; Song, Y.; Medforth, C. J.; Shelnutt, J. A., Phys. Chem. Chem. Phys. 2010, 12, 4072–4077. Raman-nanotubes.pdf |
| Self-Assembled Porphyrin Nanostructures, Medforth, C. J.; Wang, Z.; Martin, K. E.; Song, Y.; Jacobsen, J. L.; Shelnutt, J. A., Chem. Commun. 2009, 7261-7277. ChemComm-feature-article.pdf |
| Evolution of Dendritic Platinum Nanosheets into Ripening-Resistant Holey Sheets, Song, Y.; Hickner, M. A.; Challa, S. R.; Dorin, R. M.; Garcia, R. M.; Wang, H.; Jiang, Y.-B.; Li, P.; Qiu, Y.; van Swol, F.; Medforth, C. J.; Miller, J. E.; Nwoga, T.; Kawahara, K.; Li, W.; Shelnutt, J. A., Nano Lett. 2009, 9, 1534-1539. HoleySheets.pdf HoleySheets-SI.pdf |
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Silica-Metal Core-Shells and Metal Shells Synthesized by Porphyrin-Assisted Photocatalysis, Wang, H.; Song, Y.; Wang, Z.; Medforth, C. J.; Miller, J. E.; Evans, L.; Li, P.; Shelnutt, J. A., Chem. Mater. 2008, 20, 7434-7439. Pt-on-Si.pdf |
| Synthesis of Platinum Nanowheels Using a Bicellar Template, Song, Y.; Dorin, R. M.; Garcia, R. M.; Jiang, Y.-B.; Wang, H.; Li, P.; Qiu, Y.; van Swol, F.; Miller, J. E.; Shelnutt, J. A., J. Am. Chem. Soc. 2008, 130, 12602-12603. Nanowheels.pdf W-SI.pdf |
| Calcium-dependent Heme Structure in the Reduced Forms of the Bacterial Cytochrome c Peroxidase from Paracoccus pantotrophus, Pauleta, S. R.; Lu, Y.; Goodhew, C. F.; Moura, I.; Pettigrew, G. W.; Shelnutt, J. A., Biochemistry 2008, 47, 5841-5850. CcP-reduced.pdf CcP-reduced-SI.pdf |
| Light-driven Synthesis of Hollow Platinum Nanospheres, Garcia, R. M.; Song, Y.; Dorin, R. M.; Wang, H.; Li, P.; Qiu, Y.; van Swol, F.; Shelnutt, J. A., Chem. Commun. 2008, 2535-3537. ChemCommun-Spheres.pdf |
| Monodisperse Porphyrin Nanospheres Synthesized by Coordination Polymerization, Wang, Z.; Lybarger, L. E.; Wang, W.; Medforth, C. J.; Miller, J. E.; Shelnutt, J. A., Nanotechnology 2008, 19, 395604. Nanospheres.pdf Nanospheres-SI.pdf |
| Synthesis of Platinum Nanowire Networks Using a Soft Template, Song, Y.; Garcia, R. M.; Dorin, R. M.; Wang, H.; Qiu, Y.; Coker, E. N.; Miller, J. E.; Shelnutt, J. A., Nano Lett. 2007, 7, 3650-3655. NanoLett.pdf NanoLett-SI.pdf |
| Self-Assembly and Self-Metallization of Porphyrin Nanosheets, Wang, Z.; Li, Z.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2007, 129, 2440-2441. Nanosheets.pdf Nanosheets-SI.pdf |
| Interfacial Synthesis of Dendritic Platinum Nanoshells Templated on Benzene Nanodroplets Stabilized in Water by a Photocatalytic Lipoporphyrin, Wang, H.; Song, Y.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2006, 128, 9284-9285. Nanoshells.pdf Nanoshells-SI.pdf |
| Synthesis of Platinum Nanocages Using Liposomes Containing Photocatalyst Molecules, Song, Y.; Garcia, R. M.; Dorin, R. M.; Wang, H.; Qiu, Y.; Shelnutt, J. A., Angew. Chem., Int. Ed. 2006, 45, 8126-8130. Nanocages.pdf Nanocages-SI.pdf |
| Porphyrin Nanofiber Bundles from Interfacial Ionic Self-assembly and their Photocatalytic Self-metallization, Wang, Z.; Ho, K. J.; Medforth, C. J.; Shelnutt, J. A., Adv. Mater. 2006, 18, 2557-2560. Nanofibers.pdf Nanofibers-SI.pdf |
| Foamlike Nanostructures Created from Dendritic Platinum Sheets on Liposomes, Song, Y.; Steen, W. A.; Peņa, D.; Jiang, Y.-B.; Medforth, C. J.; Huo, Q.; Pincus, J. L.; Qiu,Y.; Sasaki, D. Y.; Miller, J. E.; Shelnutt, J. A., Chem. Mater. 2006, 18, 2335-2346. PtFoams.pdf SI.pdf |
| Platinum Nanodendrites, Song, Y.; Jiang, Y.-B.; Wang, H.; Pena, D. A.; Qiu, Y.; Miller, J. E.; Shelnutt, J. A., Nanotechnology 2006, 17, 1300-1308. PtDendrites.pdf |
| The Conserved Active-Site Loop Residues of Ferrochelatase Induce Porphyrin Conformational Changes Necessary for Catalysis, Shi, Z; Franco, R.; Haddad, R.; Shelnutt, J. A.; Ferreira, G. C., Biochemistry 2006, 45, 2904-2912. Fc.pdf |
| Chelatases: Distort to select?, Al-Karadaghi, S.; Franco, R.; Hansson, M.; Shelnutt, J. A.; Isaya, G.; Ferreira, G. C., TiBS 2006, 31, 135-142. Fc-TiBS.pdb |
| Energetics and Structural Consequences of Axial Ligand Coordination in Nonplanar Nickel Porphyrins, Song, Y.; Haddad, R. E.;Jia, S.-L.; Hok, S.; Olmstead, M. M.; Nurco, D. J.; Schore, N. E.; Zhang, J.; Ma,; J.-G.; Smith, K. M.; Gazeau, S.; Pecaut, J.; Marchon, J.-C.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2005, 127, 1179-1192. Lig.pdf SI.pdf |
| Selective Fluorescence Detection of Divalent and Trivalent Metal Ions with Functionalized Lipid Membranes, Pincus, J. L.; Jin, C.; Huang, W.; Jacobs, H. K.; Gopalan, A. S.; Song, Y.; Shelnutt, J. A.; Sasaki, D. Y., J. Mater. Chem. 2005, 15, 2938-2945. Pincus 2005.pdf |
| Self-Metallation of Photocatalytic Porphyrin Nanotubes, Wang, Z.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2004, 126, 16720-16721. MetalPorphyrinNanotubes.pdf SI-Metal.pdf |
| Porphyrin Nanotubes by Ionic Self-Assembly, Wang, Z.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2004, 126, 15954-15955. PorphyrinNanotubes.pdf SI-tubes.pdf |
| Controlled Synthesis of 2-D and 3-D Dendritic Platinum Nanostructures, Song, Y.; Yang, Y.; Medforth, C. J.; Pereira, E.; Singh, A. K.; Xu, H.; Jiang, Y.; Brinker, C. J.; van Swol, F.; Shelnutt, J. A., J. Am. Chem. Soc. 2004, 126, 625-635. Pt.pdf Pt-SI.pdf |
| Synthesis of Peptide-Nanotube Platinum-Nanoparticle Composites, Song, Y.; Challa, S. R.; Medforth, C. J.; Qiu, Y.; Watt, R. K.; Pena, D. A.; Miller, J. E.; van Swol, F.; Shelnutt, J. A., Chem. Commun. 2004, 1044-1045. ProteinTubes SI-Tubes |
| Origin of the Red Shifts in the Optical Absorption Bands of Nonplanar Tetraalkylporphyrins, Haddad, R.; Gazeau, S.; Pecaut, J.; Marchon, J.-C.; Medforth, C. J.; Shelnutt, J. A., J. Am. Chem. Soc. 2003, 125, 1253-1268. red-shift.pdf |
| Functional Nanocomposites Prepared by Self-Assembly and Polymerization of Diacetylene Surfactants and Silicic Acid, Yang, Y.; Lu, Y.; Lu, M.; Huang, J.; Haddad, R.; Gazeau, S.; Xomeritakis, G.; Liu, N.; Malanoski, A. P.; Sturmayr, D.; Fan, H.; Sasaki, D. Y.; Assink, R. A.; Shelnutt, J. A.; van Swol, F.; Lopez, G. P.; Burns, A. R.; Brinker, C. J., J. Am. Chem. Soc. 2003, 125, 1269-1277. diacetylene.pdf |
| Unusual Aryl-Porphyrin Rotational Barriers in Peripherally Crowded Porphyrins, Medforth, C. J.; Haddad, R.; Muzzi, C. M.; Dooley, N. R..; Jaquinod, L.; Shyr, D. C.; Nurco, D. J.; Olmstead, M. M.; Smith, K. M.; Ma, J.-G.; Shelnutt, J. A., Inorg. Chem. 2003, 42, 2227-2241. aryl-rot.pdf |
| Heme Distortions in Sperm-Whale Carbonmonoxy Myoglobin: Correlations between Rotational Strengths and Heme Distortions in MD-Generated Structures, Kiefl, C.; Sreerama, N.; Haddad, R.; Sun, L.; Jentzen, W.; Lu, Y.; Qiu, Y.; Shelnutt, J. A.; Woody, R. W., J. Am. Chem. Soc. 2002, 93, 3385-3394. ja011961w.pdf SI-color.pdf |
| Influence of Electronic and Structural Effects on the Oxidative Behavior of Nickel Porphyrins, Kadish, K. M.; Lin, M.; Van Caemelbecke, E.; De Stefano, G.; Medforth, C. J.; Nurco, D. J.; Nelson, N. Y.; Krattinger, B.; Muzzi, C. M.; Jaquinod, L.; Xu, Y.; Shyr, D. C.; Smith, K. M.; Shelnutt, J. A., Inorg. Chem. 2002, 41, 6673-6687. subst-effects.pdf |
| Binding of Protoporphyrin IX and Metal Derivatives to the Active Site of Wild-Type Mouse Ferrochelatase at Low Porphyrin-to-Protein Ratios, Lu, Y.; Sousa, A.; Franco, R.; Mangravita, A.; Ferreira, G. C.; Moura, I.; Shelnutt, J. A., Biochemistry 2002, 41, 8253-8262. low-conc.pdf |
| Twisting the Porphyrin Ring to Enhance Epoxidation Enantioselectivity, Gazeau, S.; Pecaut, J.; Haddad, R.; Shelnutt, J. A.; Marchon, J.-C., Eur. J. Inorg. Chem. 2002, 11, 2956-2960. twisting.pdf |
| Ligand-Induced Heme Ruffling and Bent NO Geometry in Ultra-High-Resolution Structures of Nitrophorin 4, Roberts, S. A.; Weichsel,A.; Qiu, Y.; Shelnutt, J. A.; Walker, F. A.; Montfort, W. R., Biochemistry 2001, 40, 11327-11337. bi0109257.pdf |
| Normal-coordinate Structural Decomposition and the Vibronic Spectra of Porphyrins, Shelnutt, J. A., J. Porphyrins Phthalocyanines 2001, 5, 300-311. vibronic.pdf |
| Self-assembly of mesoscopically ordered chromatic polydiacetylene/silica nanocomposites, Lu, Y.; Yang, Y.; Sellinger, A.; Lu, M.; Huang, J.; Fan, H.; Haddad, R.; Lopez, G.; Burns, A. R.; Sasaki, D. Y.; Shelnutt, J.; Brinker, C. J., Nature 2001, 410, 913-917. pda-nature.pdf |
| Calcium-Dependent Conformation of a Heme and Fingerprint Peptide of the Diheme Cytochrome c Peroxidase from Paracoccus pantotrophus, Pauleta, S. R.; Lu, Y.; Goodhew, C. F.; Moura, I..; Pettigrew, G. W.; Shelnutt, J. A., Biochemistry 2001, 40, 6570-6579. bi2870z.pdf |
| Conformational Distortions of Metalloporphyrins with Electron-Withdrawing NO2 Substituents at Different Meso Positions. A Structural Analysis by Polarized Resonance Raman Dispersion Spectroscopy and Molecular Mechanics Calculations, Schweitzer-Stenner, R.; Lemke, C.; Haddad, R.; Qiu, Y.; Shelnutt, J. A.; Quirke, J. M. E.; Dreybrodt, W., J. Phys. Chem. A 2001, 105, 6680-6694. jpc.pdf |
| Conformational Analysis of the Non-Planar Deformations of Cobalt Porphyrin Complexes in the Cambridge Structural Database, Cullen, D. L.; Desai, L. V.; Shelnutt, J. A.; Zimmer, M., Struct. Chem. 2001, 12, 127-136. cs2001.pdf |
| Vibrational Analysis of Metalloporphyrins with Electron-Withdrawing NO2 Substituents at Different Meso Positions, Lemke, C.; Schweitzer-Stenner, R. ; Shelnutt, J. A.; Quirke, J. M. E.; Dreybrodt, W., J. Phys. Chem. A 2001, 105, 6668-6679. JPCLemke.pdf |
| Molecular Simulations and Normal-coordinate Structural Analysis of Porphyrins and Heme Proteins, Shelnutt, J. A., in "The Porphyrin Handbook" Eds. Kadish, K. M.; Smith, K. M.; Guilard, R., Academic Press: San Diego, CA, 2000, Vol. 7, Chpt. 50. HandbookChapter.pdf |
| Molecular Simulations of Porphyrins and Heme Proteins, Shelnutt, J. A., J. Porphyrins Phthalocyanines 2000, 4, 386-389. Overview-jpp.pdf |
| Porphyrin Interactions with Wild-type and Mutant Mouse Ferrochelatase, Franco, R.; Ma, J.-G.; Lu, Y.; Ferreira, G. C.; Shelnutt, J. A., Biochemistry 2000, 39, 2517-2529. bi991346t.pdf |
| Using Cytochrome c3 to Make Selenium Nanowires, Abdelouas, A.; Gong, W. L.; Lutze, W.; Shelnutt, J. A.; Franco, R.; Moura, I., Chem. Mater. 2000, 12, 1510-1512. chemmater0900.pdf |
| Synthesis and Characterization of a Chiral Nonplanar Porphyrin, Muzzi, C. M.; Medforth, C. J.; Smith, K. M.; Jia, S.-L.; Shelnutt, J. A., Chem. Commun. 2000, 131-132. 62cc20.pdf |
| The Quantum Mixed-Spin Heme State of Barley Peroxidase: A Paradigm for Class III Peroxidases, Howes, B. D.; Schiodt, C. B.; Welinder, K. G.; Marzocchi, M. P.; Ma, J.-G.; Zhang, J.; Shelnutt, J. A.; Smulevich, G., Biophys. J. 1999, 77, 478-492. bj478.pdf |
| Synthesis and Electrochemical Studies of a Series of Fluorinated Dodecaphenylporphyrins, Kadish, K. M.; Van Caemelbecke, E.; D'Souza, F.; Lin, M.; Nurco, D. J.; Medforth, C. J.; Forsyth, T. P.; Krattinger, B.; Smith, K. M.; Fukuzumi, S.; Nakanishi, I.; Shelnutt, J. A., Inorg. Chem. 1999, 38, 2188-2198. ic9811695.pdf |
| Novel Dodecaarylporphyrins: Synthesis and Dynamic Properties, Muzzi, C. M.; Medforth, C. J.; Cancilla, M.; Lebrilla, C.; Ma, J.-G.; Shelnutt, J. A.; Smith, K. M., Tetrahedron Lett. 1999, 40, 6159-6162. tetlett799.pdf |
| Synthesis and unusual properties of the first 2,3,7,8,12,13,17,18-octabromo-5,10,15,20- tetraalkylporphyrin, Nelson, N. Y.; Medforth, C. J.; Nurco, D. J.; Jia, S.-L.; Shelnutt, J. A.; Smith, K. M., Chem. Comm. 1999, 2071-2072. NiBr8T(CF3)P.pdf |
| Resonance Raman Investigation of Nickel Microperoxidase-11, Ma, J.-G.; Vanderkooi, J. M.; Zhang, J.; Jia, S.-L.; Shelnutt, J. A. Biochemistry 1999, 38, 2787-2795. bi982332a.pdf |
| Nonplanar Porphyrins and their Significance in Proteins, Shelnutt, J. A.; Song, X.-Z.; Ma, J.-G.; Jia, S.-L.; Jentzen, W.; Medforth, C. J., Chem. Soc. Rev. 1998, 27, 31-41. csr.pdf |
| Axial Coordination and Conformational heterogeneity of Nickel(II) Tetraphenylporphyrin Complexes with Nitrogenous Bases, Jia, S.-L.; Jentzen, W.; Shang, M.; Song, X.-Z.; Ma, J.-G.; Scheidt, W. R.; Shelnutt, J. A., Inorg. Chem. 1998, 37, 4402-4412. ic980298+.pdf |
| Protein-Induced Changes in Nonplanarity of the Porphyrin in Nickel Cytochrome c Probed by Resonance Raman Spectroscopy, Ma, J.-G.; Laberge, M.; Song, X.-Z.; Jentzen, W.; Jia, S.-L.; Zhang, J.; Vanderkooi, J. M.; Shelnutt, J. A. Biochemistry, 1998, 37, 5118-5128. bi972375b.pdf |
| The Structural Origin of Nonplanar Heme Distortions in Tetraheme Ferricytochromes c3, Ma, J.-G.; Zhang, J.; Franco, R.; Jia, S.-L.; Moura, I.; Moura, J. J. G.; Kroneck, P. M. H.; Shelnutt, J. A. Biochemistry 1998, 37, 12431-12442. bi981189.pdf |
| Picosecond to Microsecond Photodynamics of a Nonplanar Nickel Porphyrin: Solvent Dielectric and Temperature Effects, Drain, C. M.; Gentemann, S.; Roberts, J. A.; Nelson, N. Y.; Medforth, C. J.; Jia, S.-L.; Simpson, M. C.; Smith, K. M.; Fajer, J.; Shelnutt, J. A.; Holten, D., J. Am. Chem. Soc. 1998, 120, 3781-3791. ja974101h.pdf Supporting information. |
| Conservation of the Conformation of the Porphyrin Macrocycle in Heme Proteins, Jentzen, W.; Ma, J.-G.; Shelnutt, J. A., Biophys. J. 1998, 74, 753-763. bj753.pdf |
| Substituent-Induced Perturbation Symmetries and Distortions of meso-tert-Butylporphyrins, Song, X.-Z.; Jentzen, W.; Jaquinod, L.; Khoury, R. G.; Medforth, C. J.; Jia, S.-L.; Ma, J.-G.; Smith, K. M.; Shelnutt, J. A. Inorg. Chem. 1998, 37, 2117-2128. ic9711978.pdf Supporting information. |
| Metal Dependence of the Contributions of Low-Frequency Normal Coordinates to the Sterically Induced Distortions of Meso-Dialkyl-Substituted Porphyrins, Song, X.-Z.; Jaquinod, L.; Jentzen, W.; Nurco, D. J.; Jia, S.-L.; Khoury, R. G.; Ma, J.-G.; Medforth, C. J.; Smith, K. M.; Shelnutt, J. A., Inorg. Chem. 1998, 37(8), 2009-2019. ic970465z.pdf Supporting information. |
| A Pyridine-Sensitive Venus Flytrap Porphyrin, Mazzanti, M.; Marchon, J.-C.; Shang, M.; Scheidt, W. R.; Jia, S.-L.; Shelnutt, J. A., J. Am. Chem. Soc. 1997, 119, 12400-12401. ja972947.pdf Supporting information-1,2. |
| Synthesis and Physical Characterization of Novel Heme-Based Model Systems for Photoinitiated Electron Transfer. 1. Complexation of a RuProHis Bifunctional Peptide and Microperoxidase-11, Fan, B.; Fontenot, D. L.; Larsen, R. W.; Simpson, M. C.; Shelnutt, J. A.; Falcon, R.; Martinez, L.; Niu, S.; Zhang, S.; Niemczyk, T.; Ondrias, M. R., Inorg. Chem. 1997, 36(18), 3839-3846. ic9700415.pdf |
| Synthesis and Physical Characterization of Novel Heme-Based Model Systems for Photoinitiated Electron Transfer. 2. Direct Ruthenation of Microperoxidase-11, Fan, B.; Simpson, M. C.; Shelnutt, J. A.; Martinez, L.; Falcon, R.; Buranda, T.; Pastuszyn, A. J.; Ondrias, M. R., Inorg. Chem. 1997, 36(18), 3847-3853. ic970040c.pdf |
| Comparative Analysis of the Conformations of Symmetrically and Asymmetrically Deca- and Undecasubstituted Porphyrins Bearing Meso-Alkyl or -Aryl Groups, Senge, M. O.; Medforth, C. J.; Forsyth, T. P.; Lee, D. A.; Olmstead, M. M.; Jentzen, W.; Pandey, R. K.; Shelnutt, J. A.; Smith, K. M., Inorg. Chem. 1997, 36(6), 1149-1163. ic961156w.pdf Supporting information-1,2,3. |
| NMR Studies of Nonplanar Porphyrins. Part 1. Axial Ligand Orientations in Highly Nonplanar Porphyrins, Medforth, C. J.; Muzzi, C. M.; Shea, Kalyn M.; Smith, K. M.; Abraham, R. J.; Jia, S.; Shelnutt, J. A., J. Chem. Soc., Perkin Trans. 2; 1997, 834-837. 48_JCSP.pdf |
| NMR Studies of Nonplanar Porphyrins. Part 2. Effect of Nonplanar Conformational Distortions on the Porphyrin Ring Current, Medforth, C. J.; Muzzi, C. M.; Shea, Kalyn M.; Smith, K. M.; Abraham, R. J.; Jia, S.; Shelnutt, J. A., J. Chem. Soc., Perkin Trans. 2; 1997, 839-844. 49_JCSP2.pdf |
| Planar and Nonplanar Conformations of (meso-Tetraphenylporphinato)nickel(II) in Solution As Inferred from Solution and Solid-State Raman Spectroscopy, Jentzen, W.; Unger, E.; Song, X.-Z.; Jia, S.-L.; Turowska-Tyrk, I.; Schweitzer-Stenner, R.; Dreybrodt, W.; Scheidt, W. R.; Shelnutt, J. A., J. Phys. Chem. A, 1997, 101, 5789-5798. jp970496f.pdf |
| Raman Dispersion Spectroscopy on the Highly Saddled Nickel(II)-Octaethyltetraphenyl- porphyrin Reveals the Symmetry of Nonplanar Distortions and the Vibronic Coupling Strength of Normal Modes, Schweitzer-Stenner, R.; Sticternath, A.; Dreybrodt, W.; Jentzen, W.; Song, X.-Z.; Shelnutt, J. A.; Nielsen, O. F.; Medforth, C. J.; Smith, K. M., J. Chem. Phys, 1997, 107, 1794-1815. 50jcp.pdf |
| Structural Characterization of Synthetic and Protein-Bound Porphyrins in Terms of the Lowest-Frequency Normal Coordinates of the Macrocycle, Jentzen, W.; Song, X.-Z.; Shelnutt, J. A., J. Phys. Chem. B, 1997, 101, 1684-1699. jp963142h.pdf Supporting information- 1,2. |
| Isolation and Characterization of Vibrational Spectra of Individual Heme Active Sites in Cytochrome bc1 Complexes from Rhodobacter capsulatus, Gao, F.; Qin, H.; Simpson, M. C.; Shelnutt, J. A.; Knaff, D. B.; Ondrias, M. R., Biochemistry 1996, 35, 12812-12819. bi960419v.pdf |
| Representation of Nonplanar Structures of Nickel(II) 5,15-Disubstituted Porphyrins in Terms of Displacements along the Lowest-Frequency Normal Coordinates of the Macrocycle, Song, X.-Z.; Jentzen, W.; Jia, S.-L.; Jaquinod, L.; Nurco, D. J.; Medforth, C. J.; Smith, K. M.; Shelnutt, J. A., J. Am. Chem. Soc. 1996, 118, 12975-12988. ja961676q.pdf Supporting information. |
| Planar Solid-State and Solution Structures of (Porphinato)nickel(II) As Determined by X-ray Diffraction and Resonance Raman Spectroscopy, Jentzen, W.; Turowska-Tyrk, I; Scheidt, W. R.; Shelnutt, J. A., Inorg. Chem. 1996, 35, 3559-3567. ic960157l.pdf Supporting information. |
| Conformational Properties of Nickel(II) Octaethylporphyrin in Solution. 1. Resonance Excitation Profiles and Temperature Dependence of Structure-Sensitive Raman Lines, Jentzen, W.; Unger, E.; Karvounis, G.; Shelnutt, J. A.; Dreybrodt, W.; Schweitzer-Stenner, R. J. Phys. Chem. 1996, 100, 14184-14191. jp9533032.pdf |
| Langmuir-Blodgett Films of Stearic Acid Containing Octakis((methoxycarbonyl)methyl)- meso-tetrakis(((eicosanyloxy)carbonyl)phenyl)porphyrin, Song, X., Miura, M.; Xu, X.; Taylor, K. K.; Majumder, S. A.; Hobbs, J. D.; Cesarano, J.A; Shelnutt, J. A., Langmuir 1996, 12, 2019-2027. la950762l.pdf |
| Correlations between Raman Frequencies and Structure for Planar and Nonplanar Metalloporphyrins, Sparks, L.D., Anderson, K.K., Medforth, C.J.; Shelnutt, J. A.; Inorg. Chem. 1994, 33, 2297-2302. ic00088a036.pdf |
| Macrocycle and Substituent Vibrational Modes of Nonplanar Nickel(II) Octaethyltetraphenylporphyrin from its Resonance Raman, Near-Infrared-Excited FT Raman, and FT-IR Spectra and Deuterium Isotope Shifts, Stichternath, A.; Schweitzer-Stenner, R.; Dreybrodt, W.; Mak, R, S.; Li, X.; Sparks, L,D.; Medforth, C. J.; Smith, K. M.; Shelnutt, J. A., J. Phys. Chem. 1993, 97, 3701-3708. j100117a012.pdf |
| Planar-Nonplanar Conformational Equilibrium in Metal Derivatives of Octaethylporphyrin and meso-Nitrooctaethylporphyrin, Anderson, K. K.; Hobbs, J. D.; Luo, L.; Stanley, K. D.; Quirke, J. M.., Shelnutt, J. A., J. Am. Chem. Soc. 1993, 115, 12346-12352. ja00079a015.pdf |
| Excited-State Transient of Vanadyl Uroporphyrin I Detected by Resonance Raman Spectroscopy, Alden, R. G.; Sparks, L. D.; Ondrias, M. R.,; Shelnutt, J. A., J. Phys. Chem. 1990, 94, 1440-1443. j100367a44.pdf |
| Influences of p-p Complex Formation, Dimerization, and Binding to Hemoglobin on the Planarity of Nickel(II) Porphyrins, Alden, R. G.; Ondrias, M. R.; Shelnutt, J. A., J. Am. Chem. Soc. 1990, 112, 691-697. ja00158a030.pdf |
| Transient Raman Difference Spectroscopy of Nickel(II) Uroporphyrin p-p Complexes, Crawford, B.A.; Ondrias, M. R.; Shelnutt, J. A., J. Phys. Chem. 1990, 94, 6647-6652. ja00213a059pdf |
| Ruffling of Nickel (II) Octaethylporphyrin in Solution, Alden, R. G.; Crawford, B.A., Ondrias, M. R.; Shelnutt, J. A., J. Am. Chem. Soc. 1989, 111,2070-2072. ja00188a020.pdf |
| Synthesis and Spectroscopic Characterization of Bis-Pocket Porphyrins: Tetrakis (2,6-dinitrophenyl)porphyrin and Catalytic Activity of a Manganese(III) Chloride Derivative in Alkane Oxidation, Carlos, A.; Quintana, Roger, A.; Assink, Shelnutt, J. A., Inorg. Chem. 1989, 28, 3421-3425. ic00317a006.pdf |
| Photodynamics of a Nickel Hydrocorphinoid Model of F430, Crawford, B.A., Findsen, E.W., Ondrias, M.R., Shelnutt, J. A.; Inorg. Chem. 1988, 27, 1842-1846. ic00284a002.pdf |
| Sensitization and Photoredox Reactions of Zinc(II) and Antimony(V) Uroporphyrins in Aqueous Media, Kalyanasundaram, K.; Grätzel, M.; Shelnutt, J. A., Inorg. Chem. 1988, 27, 2820-2825. ic00289a016.pdf |
| New Crystalline Phase of (Octaethylporphinato)nickel( 11). Effects of p-p Interactions on Molecular Structure and Resonance Raman Spectra , Brennan, T. D.; Scheidt, W. R.; Shelnutt, J. A., J. Am. Chem. Soc. 1988, 110, 3920-3924. NiOEP-xtal.pdf |
| Axial Ligation-Induced Structural Changes in Nickel Hydrocorphinoids Related to Coenzyme F430 Detected by Raman difference spectroscopy, Shelnutt, J. A., J. Am. Chem. Soc. 1987, 109, 4169-4173. ja00248a007.pdf |
| Substituent Effects on the Electronic Structure of Metalloporphyrins: A Quantitative Analysis in Terms of Four-Orbital-Model Parameters, Ortiz, V., Shelnutt, J. A.; J. Phys. Chem. 1985, 89, 4733-4739. j100268a017.pdf |
| Raman Spectroscopy of Polymers of Metal Protoporphyrin Free Acids on Metal Electrodes, Ginley, D. S.; Shelnutt, J. A., J. Phys. Chem. 1985, 89, 5473-5476. j100271a031.pdf |
| Aggregation of Uroporphyrin I Its Metal Derivatives In Aqueous Solution: Raman Difference Spectroscopy and Absorption Spectroscopy, Dobry, M. M., Satterlee, J. D., Shelnutt, J. A., J. Phys. Chem. 1984, 88, 4980-4987. j150665a038.pdf |
| Electronic Structure of Metallouroporphyrins and Their p-p Dimers, Shelnutt, J. A., J. Phys. Chem. 1984, 88, 4988-4992. j150665a039.pdf |
| Studies of Urohemin I in Aqueous Solution. Thermodynamic of Self-Association and Electronic Properties of Two Species Detected by Proton NMR Spectroscopy, Satterlee, J.D.; Shelnutt, J. A., J. Phys. Chem. 1984, 88, 5487-5492. j150667a008.pdf |
| Electronic Structure of the Porphyrin Ring in an Electrostatically Bound p-p Complex. Methylviologen-Metallouroporphyrin Complexes, Shelnutt, J. A., J. Phys. Chem. 1984, 88, 6121-6127. j150669a014.pdf |
| Unusual Coordination and Metal-Ligand Geometry of a Vanadyl Porphyrin in Aqueous Solution, Dobry, M. M.; Shelnutt, J. A.; J. Phys.Chem. 1983, 87, 3012-3015. j100239a008.pdf |
| Correlation between Metal Stability, Charge Transfer, and Raman Frequencies in Metalloporphyrins and their p-p Complexes, Shelnutt, J. A., J. Am. Chem. Soc. 1983, 105, 774-778. ja00342a020.pdf |
| Photoreduction of Methylviologen Sensitized by Dihydroxytin( IV) Uroporphyrin, Shelnutt, J. A., J. Am. Chem. Soc. 1983, 105, 7179-7180. ja00362a031.pdf |
| Structure of Molecular Complexes of Copper Uroporphyrin with Aromatic Heterocycles, Shelnutt, J. A., J. Am. Chem. Soc. 1981, 103, 4275-4277. ja00404a062.pdf |
| A Simple interpretation of Raman excitation spectra of metalloporphyrins, Shelnutt, J. A., J. Chem. Phys. 1981, 74, 6644-6657 Simple-jcp.pdf |
| The Raman excitation spectra and absorption spectrum of a metalloporphyrin in an environment of low symmetry, Shelnutt, J. A., J. Chem. Phys. 1980, 72, 3949-3958 LowSymmetry-jcp.pdf |
| Resonance Raman spectra of copper tetraphenylporphyrin: Effects of strong vibronic coupling on excitation profiles and the absorption spectrum, Shelnutt, J. A., J. Chem. Phys. 1978, 69, 5361-5374 StrongCoupling-jcp.pdf |
| Resonance Raman spectra of metalloporphyrins. Effects of Jahn-Teller instability and nuclear distortion on excitation profiles of Stokes fundamentals, Cheung, L. D.; Chang, C. C.; Yu, N.-T.; Shelnutt, J. A., J. Chem. Phys. 1977, 66, 3387-3398 Jahn-Trllrt-jcp.pdf |
| Resonance Raman spectra of manganese (III) etioporphyrin I, Shelnutt, J. A.; O'Shea, D. C.; Cheung, L. B.; Yu, N. T.; Felton, R. H., J. Chem. Phys. 1976, 64, 1156-1165 MnPorphyrin-jcp.pdf |
| Structure Implication in Metalloporphyrins of the 1590cm-1 Anomalously Polarized Resonance Raman Line, Felton, R.H., Yu, N.T., O'Shea, D.C., Shelnutt, J.A., J. Am. Chem. Soc. 1974, 196, 3675-3676. ja000818a065.pdf |
| Also see complete list of publications. |